Hi,
change your item as follow:
FromURL: /PhpGedView/*
ToURL: http://{siteurl}/component/phpgedview/
FromURL must match with REQUEST_URI and you can use regexp, but macro {siteurl} is for ToURL.
Also, remember that using regular expression you can redirect many URLs to the same destination, BUT at the moment ToURL must specify a single URL.
I mean, it's not possible with just one item to redirect /oldpath/pageX.php to /newpath/pageX.php (maybe in the next release). You must create an item for every destination.
Regards,
Luigi